From WhyAskWhy.org Wiki
I haven't watched all of these, so I'm not necessarily endorsing any of them
- C# Fundamentals: Development for Absolute Beginners 
- thenewboston - website dedicated to providing free, quality tutorial videos on a broad range of subjects
- Programming Video Tutorials (PVT) - Covers many popular programming languages through both text and video tutorials.
- Visual Studio Developer Center > Learn > How Do I Videos for Visual Studio 2010 > "How Do I?" Videos for Visual C#
- A very well produced series for absolute beginners. This series uses the Microsoft Visual C# 2010 Express IDE for all of the lessoons.